Unit 6 · Thermodynamics
Lesson 56 of 91

6.8 Enthalpy of Formation

01Building from elements

ΔH°f is the enthalpy change to form 1 mol of a compound from its elements in standard states. ΔH°f of an element in its standard state = 0 (O₂(g), C(graphite)).

ΔH°rxn = Σ n·ΔH°f(products) − Σ n·ΔH°f(reactants).

02Notebook box

Multiply each ΔH°f by its coefficient.

Worked example: CH₄ + 2O₂ → CO₂ + 2H₂O(l): [−393.5 + 2(−285.8)] − [−74.8 + 0] = −890.3 kJ.

Key takeaways
  • ✦Elements = 0.
  • ✦Products − reactants.
  • ✦Multiply by coefficients.
Quick check

Did it stick?

1.ΔH°f of O₂(g)?

2.ΔH°f(products) total −500, reactants −200. ΔH°rxn?

3.Which has ΔH°f = 0?