Unit 3 · Intermolecular Forces & Properties
Lesson 26 of 91

3.11 Spectroscopy & the EM Spectrum

01Light matches transitions

Different energies of light cause different changes: microwaves → rotation, infrared → bond vibration, UV/visible → electron transitions.

Energy and wavelength are inversely related: shorter wavelength = higher energy.

02Notebook box

c = λν, E = hν. h = 6.626 × 10^−34 J·s, c = 3.00 × 108 m/s.

Worked example: Which causes electron transitions, IR or UV? UV — higher energy.

Key takeaways
  • ✦Microwave rotate, IR vibrate, UV/Vis electrons.
  • ✦Short λ = high E.
  • ✦E = hν.
Quick check

Did it stick?

1.IR radiation causes molecules to…

2.Highest energy?

3.Doubling frequency does what to energy?