Unit 6 · Thermodynamics
Lesson 53 of 91

6.5 Energy of Phase Changes

01Flat lines on heating curves

During melting or boiling, temperature stays constant: added energy overcomes IMFs instead of increasing KE.

Vaporization takes much more energy than fusion because particles must fully separate.

02Notebook box

q = n·ΔH_fus or n·ΔH_vap on plateaus; q = mcΔT on slopes.

Worked example: Melting 2.0 mol ice (ΔH_fus = 6.01 kJ/mol) needs 12.0 kJ.

Key takeaways
  • ✦Plateaus = phase changes.
  • ✦Energy goes into IMFs.
  • ✦ΔH_vap > ΔH_fus.
Quick check

Did it stick?

1.During boiling, temperature…

2.Why is ΔH_vap > ΔH_fus?

3.Condensation is…