Unit 1 · Atomic Structure & Properties
Lesson 5 of 91

1.5 Atomic Structure & Electron Configuration

01Shells, subshells, orbitals

Electrons occupy shells (n = 1, 2, 3…) split into subshells s, p, d, f holding 2, 6, 10, 14 electrons. Fill lowest energy first (Aufbau), one per orbital before pairing (Hund), max two with opposite spins (Pauli).

Coulomb's law is the reason behind everything: attraction ∝ (charge × charge) / distance². Closer electrons and more protons mean stronger pull.

02Notebook box

Order: 1s 2s 2p 3s 3p 4s 3d 4p. Fe = [Ar] 4s² 3d⁶.

Worked example: Fe³⁺? Remove 4s first, then 3d → [Ar] 3d⁵.

Key takeaways
  • ✦Fill by energy, not shell number.
  • ✦Coulomb's law explains attraction.
  • ✦Transition metals lose 4s before 3d.
Watch outWriting Fe³⁺ as [Ar] 4s² 3d³ is the #1 error — 4s leaves first.
Quick check

Did it stick?

1.Configuration of O?

2.Max electrons in a d subshell?

3.Zn²⁺ configuration?