Unit 2 · Molecular & Ionic Compound Structure
Lesson 13 of 91

2.5 Lewis Diagrams

01Drawing them

Count total valence electrons, connect atoms with single bonds (least electronegative in the center, never H), complete octets on outer atoms, then put leftovers on the center. Use multiple bonds if the center lacks an octet.

Exceptions: B often has 6; elements in period 3+ can exceed 8 (SF₆).

02Notebook box

Total e⁻ = Σ valence (+ charge for anions, − for cations).

Worked example: CO₂ has 16 e⁻ → O=C=O with two lone pairs on each O.

Key takeaways
  • ✦Count electrons first.
  • ✦H is never central.
  • ✦Expanded octets only for period 3+.
Quick check

Did it stick?

1.Valence electrons in NH₄⁺?

2.Lone pairs on N in NH₃?

3.Which can exceed an octet?