Unit 1 · Atomic Structure & Properties
Lesson 7 of 91

1.7 Periodic Trends

01Explain with charge and distance

Across a period: protons increase, shielding barely changes → stronger pull → smaller radius, higher ionization energy and electronegativity.

Down a group: a new shell is added → electrons are farther away → larger radius, lower ionization energy.

02Notebook box

Radius ↓ across, ↑ down. Ionization energy & electronegativity ↑ across, ↓ down. Cations are smaller than their atoms; anions are larger.

Worked example: Why is Mg's 3rd ionization energy huge? Removing a 3rd electron breaks into the n = 2 core, much closer to the nucleus.

Key takeaways
  • ✦Justify with Coulomb's law, not 'it wants a full shell'.
  • ✦Big IE jump = entering core.
  • ✦Ions change size.
Watch out'Atoms want an octet' earns no AP points. Use protons, distance and shielding.
Quick check

Did it stick?

1.Largest radius?

2.Highest first ionization energy?

3.A huge jump between IE₂ and IE₃ suggests group…